欧盟空气质量监测现状及加强我国空气质量监测体系建设的建议

从欧盟空气质量监测政策和监测网络建设现状两个方面描述了欧盟空气质量监测发展现状。分析了我国空气污染现状和空气质量监测体系中存在的问题,并借鉴欧盟的经验,提出了加大政策支持和财政保障力度、逐步健全空气质量监测网络体系、加强空气质量监测技术研究、完善空气质量监测数据库、开展能力建设、提高公众参与度等加强我国空气质量监测体系建设的建议。     

水中藻类对连续流动法测定总氮结果的影响

以天津市河道、水库为研究对象,在藻类增殖期采用连续流动法与碱性过硫酸钾消解法对水体中总氮进行比对监测,同时分析水中藻类分类和藻细胞密度。试验表明:虽然两种方法测定总氮的结果精密度基本相同,但二者之间的系统误差存在显著差异,连续流动法较碱性过硫酸钾消解法的测定结果低5.4%。两种方法测定总氮结果的相对偏差与水体中藻细胞密度呈正相关性,当水体中藻细胞密度﹥2.41×108L-1时,对连续流动法测定总氮的结果产生显著影响,相对偏差超过标准规范要求。     

加速溶剂同时萃取和净化-气相色谱-三重四极杆串联质谱测定土壤和沉积物中8种多溴联苯醚

建立了土壤和沉积物中8种多溴联苯醚(PBDEs,BDE-28、BDE-47、BDE-99、BDE-100、BDE-153、BDE-154、BDE-183和BDE-209)加速溶剂同时萃取和净化-气相色谱-三重四极杆串联质谱(ASE-GC-MS-MS)的分析方法。通过优化加速溶剂萃取与弗罗里硅土在线净化和串联质谱多反应监测模式的条件,较好地去除基质干扰,并提高了三重四极杆串联质谱定性的准确性及定量的灵敏性。该方法采用改进的色谱柱能同时分析包括高溴代联苯醚BDE-209在内的8种PBDEs,其浓度范围为1～100 ng/mL(BDE-209为10～1 000 ng/mL),线性良好,线性回归系数均大于0.997。方法检出限为0.004～0.1 ng/g,方法回收率为75%～110%,方法精密度为2.4%～15.6%。适于批量处理土壤和沉积物中含有多组分痕量PBDEs的样品。     

Auxinic herbicides induce oxidative stress on Cnesterodon decemmaculatus (Pisces: Poeciliidae)

Environmental Science and Pollution Research - Pesticides might increase the production of reactive oxygen species (ROS). Dicamba (DIC) and 2,4-dichlorophenoxyacetic acid (2,4-D) are auxinic...     

Understanding implications of consumer behavior for wildlife farming and sustainable wildlife trade

Unsustainable wildlife trade affects biodiversity and the livelihoods of communities dependent upon those resources. Wildlife farming has been proposed to promote sustainable trade, but characterizing markets and understanding consumer behavior remain neglected but essential steps in the design and evaluation of such operations. We used sea turtle trade in the Cayman Islands, where turtles have been farm raised for human consumption for almost 50 years, as a case study to explore consumer preferences toward wild‐sourced (illegal) and farmed (legal) products and potential conservation implications. Combining methods innovatively (including indirect questioning and choice experiments), we conducted a nationwide trade assessment through in‐person interviews from September to December 2014. Households were randomly selected using disproportionate stratified sampling, and responses were weighted based on district population size. We approached 597 individuals, of which 37 (6.2%) refused to participate. Although 30% of households had consumed turtle in the previous 12 months, the purchase and consumption of wild products was rare (e.g., 64–742 resident households consumed wild turtle meat [i.e., 0.3–3.5% of households] but represented a large threat to wild turtles in the area due to their reduced populations). Differences among groups of consumers were marked, as identified through choice experiments, and price and source of product played important roles in their decisions. Despite the long‐term practice of farming turtles, 13.5% of consumers showed a strong preference for wild products, which demonstrates the limitations of wildlife farming as a single tool for sustainable wildlife trade. By using a combination of indirect questioning, choice experiments, and sales data to investigate demand for wildlife products, we obtained insights about consumer behavior that can be used to develop conservation‐demand‐focused initiatives. Lack of data from long‐term social–ecological assessments hinders the evaluation of and learning from wildlife farming. This information is key to understanding under which conditions different interventions (e.g., bans, wildlife farming, social marketing) are likely to succeed.     

Seasonal dynamics of phytoplankton in response to environmental variables in contrasting coastal ecosystems

Environmental Science and Pollution Research - Seasonal distribution of phytoplankton community and size structure was assessed in three different tropical ecosystems of the western Bay of Bengal...     

冻融循环作用下尾矿砂抗剪强度和变形特性研究

为探究冻融循环后尾矿物理力学特性的变化特征,使用高低温试验箱和应变控制式三轴剪力仪对处于不同初始条件下的尾矿砂进行不排水不固结试验,揭示了尾矿砂的抗剪强度参数、不同围压条件下的变形模量与冻融循环次数、含水率之间的关系。结果表明:相同含水率条件下,随冻融循环次数增加,尾矿砂黏聚力先减小后趋于稳定,内摩擦角先增大后减小,围压100 k Pa和200 k Pa时变形模量逐渐减小,围压300 k Pa时变形模量呈现先减小后缓慢增大的趋势;相同冻融循环次数条件下,随尾矿砂含水率增加,其黏聚力先增加后减小、内摩擦角不断减小;不同围压条件下变形模量在总体上均呈现出不断减小的变化趋势,围压200 k Pa时变形模量总的衰减量最大,100k Pa次之,300 k Pa最小。     

珠江口表层水中多环芳烃的分布特征及健康风险评估

分别于2015年2、5、8、11月在珠江八大入海口采集表层水体样品,应用固相萃取富集法对该区域表层水体中16种USEPA优控多环芳烃(PAHs)的时空分布特征进行分析,并利用终生致癌风险增量模型(ILCR)对该区域的饮水健康风险进行评价。结果表明:珠江口4个季度所采集的水样中,∑15PAHs的浓度范围为18.0~50.3 ng/L,含量处于中等水平。其中7种强致癌性∑7PAHs的浓度范围为1.53~3.73 ng/L,占∑15PAHs的5.89%~11.1%,∑15PAHs和∑7PAHs在枯水期(2、11月)样品中明显高于丰水期(5、8月)。就组成特征而言,各采样点PAHs以3、4环为主。珠江口表层水中非致癌类PAHs的危害商数值为0.99×10~(-5)~2.73×10~(-5),远低于USEPA规定的阈值(1);致癌类PAHs产生的健康风险为6.50×10~(-8)~2.37×10~(-7),其中Ba P导致的饮水途径健康风险最高,所有点位致癌类PAHs的健康风险均低于USEPA推荐的对致癌物质最大可接受风险水平(10~(-6)),表明珠江口表层水中PAHs尚不具备严重的致癌风险,但是仍然存在潜在的健康风险,需要重点控制和管理。     

南京典型站点春季大气颗粒物数谱分布特征

利用TSI公司的APS和SMPS系统,于2017年4月在江苏省环境监测中心点位连续一个月进行大气颗粒物数谱观测,结果表明,南京市春季典型月份大气颗粒物数浓度和体积浓度均值分别为1.64×104cm~(-3)和1.65×106μm~3/m~3;核模态、爱根核膜态、积聚模态和粗粒子模态数浓度占比分别为22.72%,53.52%,23.72%和0.05%,体积浓度占比分别为0.01%,1.76%,55.82%和42.41%;颗粒物数浓度平均日变化呈现双峰结构;PM_(2.5)体积浓度和质量浓度具有高度相关性;存在明显的新生粒子事件,3~10 nm颗粒物数浓度小时均值短时7 500 cm~(-3)。